Determination of copper, cadmium and zinc in abelmoschus esculentus l. moench using flame atomic absorption spectrophotometry

Mohd Haziq Assadiq Abd Razak, Razali Ismail

Abstract


Heavy metals such as cadmium, copper and zinc are important environmental pollutants, particularly in areas where vegetables are irrigated with wastewater. The uptake of these heavy metals especially into the human food chain was done through these leafy vegetables and they may cause harmful effects on health. This study investigates the concentration of heavy metals in Okra (Abelmoschus esculentus L. Moench) samples that were planted and compared with those bought from supermarket. The samples were tested for Zn, Cu and Cd determination using Flame Atomic Absorption Spectrometry (F-AAS). The okra samples were digested with 65%  nitric acid and diluted to the mark with distilled water.  The results obtained show that the mean values of heavy metals studied for commercial okra obtained from the supermarket are generally higher than the okra’s that are self-planted. The concentration of Cu, Zn and Cd metals detected in our own planted okra are 74.34 μg/g, 111.51 μg/g and 39.18 μg/g respectively, as compared to the okra obtained from the supermarket with metals concentration of Cu at 455.39 μg/g, Zn 275.50 μg/g and Cd 28.95 μg/g respectively. The results indicated that the concentration obtained from both samples are still above the permissible limit as outlined in Food and Agriculture Organization of United Nations (FOA) and World Health of Organization (WHO) except for concentration of Cd in commercial, and both okra samples are not safe for human consumption. 


Keywords


Abelmoschus esculentus L. Moench; heavy metals; Flame Atomic Absorption Spectrometry; concentration

Full Text:

PDF

References


Das, A. K. (1990). Metal ion induced toxicity and detoxification by chelation therapy. In: (1st eds.) A text book on medical aspects of bioinorganic chemistry.

Järup, L. (2003). Hazards of heavy metal contamination. British Medical Bulletin.

Agrawal, M. (2003). Enhancing food chain integrity: quality assurance mechanism for air pollution impacts on food and vegetable system. United Kingdom: Department for International Development.

Kabata-Pendias, A., & Pendias, H. (2001). Trace elements in soils and plants. New York(Vol. 2nd, p. 331).

ML, P., & A., K. (2003). Cow praising and importance of Panchyagavya as medicine. Sachitra Ayurveda, 5, 56–59.

Arapitsas, P. (2008). Identification and quantification of polyphenolic compounds from okra seeds and skins. Food Chemistry, 110(4), 1041–1045.

Gopalan, C. (1989). Nutritive value of Indian foods. National Institute of Nutrition.

Malaysia, M. of A. (2010). Perangkaan agromakanan 2010. Malaysia: Unit Pengurusan Maklumat dan Statistik.

Kaur, S., Gupta, A. K., & Kaur, N. (1998). Gibberellic acid and kinetin partially reverse the effect of water stress on germination and seedling growth in chickpea. Plant Growth Regulation, 25(1), 29–33.

Organization, W. H. (2006). Guidelines for the safe use of waste water, excreta and greywater. Volume 2 Wastewater use in agriculture, 2, 23.

Gardiner, D. T., Miller, R. W., Badamchian, B., Azzari, A. S., & Sisson, D. R. (1995). Effects of Repeated Sewage-Sludge Applications on Plant Accumulation of Heavy-Metals. Agriculture Ecosystems & Environment, 55(1), 1–6..

Page, J. B. (1952). Role of Physical Properties of Clays in Soil Science. Clays and Clay Minerals, 1(1), 167–176.

Rupa, T. R., Rao, C. S., Rao, A. S., & Singh, M. (2003). Effects of farmyard manure and phosphorus on zinc transformations and phyto-availability in two alfisols of India. Bioresource Technology, 87(3), 279–288.


Refbacks

  • There are currently no refbacks.


Copyright (c) 2017 eProceedings Chemistry

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

Copyright © 2016 Department of Chemistry, Universiti Teknologi Malaysia.

Disclaimer : This website has been updated to the best of our knowledge to be accurate. However, Universiti Teknologi Malaysia shall not be liable for any loss or damage caused by the usage of any information obtained from this web site.
Best viewed: Mozilla Firefox 4.0 & Google Chrome at 1024 × 768 resolution.